Open the Group Policy Management tool and either create a new policy or edit and exiting one.
Expand User Configuration => Preferences => Windows Settings => Registry
Right-click in the area on the right and select New => Registry Item
Set the action as Update
Leave the Hive as HKEY_CURRENT_USER
Set to Key Path to Software\Policies\Microsoft\Office\16.0\common\general for Office 2016, or Software\Policies\Microsoft\Office\15.0\common\general for Office 2013
Set the Value name to PreferCloudSaveLocations
Set the Value type t0 REG_DWORD
Set the Base to Hex
Set the Value data to 00000000
Click OK